Geochemical and Economic Assessment of Iron-Rich Bodies in Choman-Rayat Area, Kurdistan Region, Iraq
Main Article Content
Abstract
This paper reports the finding of potential economic iron mineralization in the ophiolite rocks system in the Choman-Rayat Area, Kurdistan, Iraq. XRD, SEM-EDS, ICP-MS, ICP-OES, and detailed optical microscopy studies indicated that these iron-rich bodies are sedimentary and formed in a hydrothermal alteration system of the abundant serpentinized peridotite in the area with possible microbial interaction. Hematite (up to 55%) is the major mineral in iron-rich bodies, along with quartz, chlorite, and some minor spinel content. In addition to Fe, other potential economic metals associated with iron-rich bodies are nickel (Ni) and cobalt (Co) mineralization. The Ni and Co concentrations ranged from 2094 to 989 ppm and 189.1 to 678.5 ppm respectively. This study adds significant data to the scarcely known or geochemically assessed mineral resources in the Iraqi Kurdistan
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
References
1. Bolton, C., Geological map, kurdistan series, scale 1/100000, sheet k6 halabja. 1954.
2. Bolton, C., Report on the geology and economic prospect of the qala dizeh area site inv. Co. Report, SOM, 1955.
3. Vasiliev, M. and V. Pentelkov, Prospecting-exploration of the bard-i-zard chromite occurrence & adjacent areas in 1961. 1962.
4. Jassim, S.Z. and J.C. Guff, Geology of iraq. Dolin Prague and Moravian Museum: Brno, Czech., 2006.
5. Fouad, S., Tectonic map of iraq, scale 1: 1000 000, 3rd edit. GEOSURV, Baghdad, Iraq, 2012.
6. Al-Bassam, K., Mineral resources of kurdistan region, iraq. Iraqi Bulletin of Geology and Mining, 2013. 9(3): p. 103-127.
7. Shingaly, W.S., A.I. Al-Juboury, and E.M. Elias, The role of carbonate-host rocks on the genesis of pb-zn deposits, northern thrust zone, kurdistan region, iraq. Journal of Tethys: Vol, 2015. 3(1): p. 031-047.
8. MNR, Occurrences of metallic deposits in the kurdistan region, iraq. Kurdistan regional government. 2016.
9. Pirouei, M.K., Kamal Kalaitzidis, Stavros P Abdullah, Shorish Mustafa, Newly discovered gossanite-like and sulfide ore bodies associated with microbial activity in the zagros ophiolites from the rayat area of ne iraq. Ore Geology Reviews, 2021. 135: p. 104191.
10. Etabi, W., Iron ore deposit&occurrences of iraq. 1982.
11. Al-Bassam, K., Final report on the regional geological survey of iraq. Vol. 5 economic geology of iraq. 1984.
12. Alavi, M., Tectonics of the zagros orogenic belt of iran: New data and
interpretations. Tectonophysics, 1994. 229(3-4): p. 211-238.
13. Alavi, M., Regional stratigraphy of the zagros fold-thrust belt of iran and its proforeland evolution. American journal of Science, 2004. 304(1): p. 1-20.
14. Othman, A.A. and R. Gloaguen, Automatic extraction and size distribution of landslides in kurdistan region, ne iraq. Remote Sensing, 2013. 5(5): p. 2389-2410.
15. Pirouei, M., K. Kolo, and S.P. Kalaitzidis, Hydrothermal listvenitization and associated mineralizations in zagros ophiolites: Implications for mineral exploration in iraqi kurdistan. Journal of Geochemical Exploration, 2020b. 208: p. 106404.
16. Moores, E.M., L.H. Kellogg, and Y. Dilek, Tethyan ophiolites, mantle convection, and tectonic" historical contingency": A resolution of the" ophiolite conundrum". SPECIAL PAPERS-GEOLOGICAL SOCIETY OF AMERICA, 2000: p. 3-12.
17. Sissakian, V., Geological map of iraq (1: 1000000) sheet no. 1. 2000, GEOSURV, Baghdad.
18. McDonough, W.F. and S.-S. Sun, The composition of the earth. Chemical geology, 1995. 120(3-4): p. 223-253.
19. Rudnick, R. and S. Gao, Composition of the continental crust in treatise on geochemistry editors-in-chief: Heinrich holland and karl turekian. 2014.
20. McKenzie, R., The adsorption of lead and other heavy metals on oxides of manganese and iron. Soil Research, 1980. 18(1): p. 61-73.
21. Ayupova, N. and V. Maslennikov. Biomineralization in ferruginous-siliceous sediments of massive sulfide deposits of the urals. in Doklady Earth Sciences. 2012. Springer Nature BV.
22. Hollis, S.P., et al., Distribution, mineralogy and geochemistry of silica-iron exhalites and related rocks from the tyrone igneous complex: Implications for vms mineralization in northern ireland. Journal of Geochemical Exploration, 2015. 159: p. 148-168.
23. Eggleton, R.A., Regolith mineralogy. Regolith Science. CSIRO Publishing, Australia, 2009: p. 45-72.
24. Krajewski, K.P., et al., Biological processes and apatite formation in sedimentary environments. Eclogae Geologicae Helvetiae, 1994. 87(3): p. 701-746.
25. Wood, S.A., The aqueous geochemistry of the rare-earth elements and yttrium: 2. Theoretical predictions of speciation in hydrothermal solutions to 350 c at saturation water vapor pressure. Chemical Geology, 1990. 88(1-2): p. 99-125.
26. Afify, A., M.E. Sanz-Montero, and J. Calvo, Differentiation of ironstone types by using rare earth elements and yttrium geochemistry–a case study from the bahariya region, egypt. Ore Geology Reviews, 2018. 96: p. 247-261.
27. Wei, S., et al., Geochemical characteristics of rare earth elements in the chaluo hot springs in western sichuan province, china. Frontiers in Earth Science, 2022: p. 425.
28. Russell, M., M. Solomon, and J. Walshe, The genesis of sediment-hosted, exhalative zinc+ lead deposits. Mineralium Deposita, 1981. 16(1): p. 113-127.
29. Loberg, B.E. and A.-K. Horndahl, Ferride geochemistry of swedish precambrian iron ores. Mineralium deposita, 1983. 18(3): p. 487-504.
30. Bajwah, Z., P. Seccombe, and R. Offler, Trace element distribution, co: Ni ratios and genesis of the big
cadia iron-copper deposit, new south wales, australia. Mineralium Deposita, 1987. 22(4): p. 292-300.
31. Wu, T., et al., Origin and enrichment of vanadium in the lower cambrian black shales, south china. ACS omega, 2021. 6(41): p. 26870-26879.
32. Zhang, J., et al., Microbial reduction and precipitation of vanadium by mesophilic and thermophilic methanogens. Chemical Geology, 2014. 370: p. 29-39.
33. Breit, G.N. and R.B. Wanty, Vanadium accumulation in carbonaceous rocks: A review of geochemical controls during deposition and diagenesis. Chemical Geology, 1991. 91(2): p. 83-97.
34. Awan, R.S., et al., The occurrence of vanadium in nature: Its biogeochemical cycling and relationship with organic matter—a case study of the early cambrian black rocks of the niutitang formation, western hunan, china. Acta Geochimica, 2021. 40(6): p. 973-997.
35. Premović, P.I., M.S. Pavlović, and N.a.Z. Pavlović, Vanadium in ancient sedimentary rocks of marine origin. Geochimica et Cosmochimica Acta, 1986. 50(9): p. 1923-1931.
36. Magnusson, N.H., Magnusson, nh mellersta och södra sverige. Vol. 1. 1973: Almqvist & Wiksell.
37. Chi Fru, E.K., Stephanos Ivarsson, Magnus Rattray, Jayne E Gkika, Katerina McDonald, Iain He, Qian Broman, Curt, Sedimentary mechanisms of a modern banded iron formation on milos island, greece. Solid Earth, 2018. 9(3): p. 573-598.
38. Posth, N.R., K.O. Konhauser, and A. Kappler, Microbiological processes in banded iron formation deposition. Sedimentology, 2013. 60(7): p. 1733-1754.
39. Pirouei, M., K. Kolo, and S.P. Kalaitzidis, Chromium-rich muscovite mineralization in zagros ophiolites in iraqi kurdistan: A study on fuchsite paragenetic association with listvenite types. Arabian Journal of Geosciences, 2020a. 13(17): p. 1-13.
40. Aswad, K.J., N.R. Aziz, and H.A. Koyi, Cr-spinel compositions in serpentinites and their implications for the petrotectonic history of the zagros suture zone, kurdistan region, iraq. Geological magazine, 2011. 148(5-6): p. 802-818.
41. Mohammad, Y.O., Serpentinites and their tectonic signature along the northwest zagros thrust zone, kurdistan region, iraq. Arabian Journal of Geosciences, 2011. 4(1): p. 69-83.
42. Aziz, N.R., K.J. Aswad, and H.A. Koyi, Contrasting settings of serpentinite bodies in the northwestern zagros suture zone, kurdistan region, iraq. Geological Magazine, 2011. 148(5-6): p. 819-837.