study of some mechanical and thermal properties for a composite material of a polymeric basis reinforced by natural material shells
Main Article Content
Abstract
This study includes the possibility of using the agricultural residues shell (walnut and pistachio) as a filler in epoxy resins as an alternative to wood and plastic based ingredients. specimens of composite materials were prepared by using hand lay-up method .These specimens were represented by two groups of composite materials that consist of epoxy resin as a material matrix reinforced with walnut shell powder once, and pistachio shell powder again with different weight ratios (11%, 15% and 19%). Mechanical tests (impact, hardness, bending) and some physical tests (thermal conductivity, absorption) were carried out. All the results were done at the temperature of the lab. The results of the specimens tests prepared showed an improvement in the impact strength when adding the minutes of the pistachio shell by ratio 15% where it reached (12.9 KJ/m2), while it saw a decrease in the composite reinforced by walnut shell powder at the same ratio (6.3 KJ/m2), The hardness of the composites also improved at the addition ratio 19% where it reached (83.2 N/m2) in the composites reinforced by the minutes of the walnut shell and (81.9 N/m2) in the composites reinforced by minutes of pistachio shell, Bending resistance also increased to the highest value at the addition ratio 19% to (56.82 N/mm2) in the composites reinforced by the minutes of the walnut shell and (54.4 N/mm2) in the composites reinforced by the minutes of the pistachio shell..On the other hand, physical measurement showed a slight increase in the values of thermal conductivity and absorption. The results indicate that the composite material reinforced with pistachio shell powder have higher values in impact, bending and thermal conductivity tests and lower values for hardness and water absorption tests when compared with composite material reinforced with walnut shell powder.
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
References
[1] Shubbar, S. D. A. (2018). Experimental Investigation of Rice Husk Particles as Filler in Hybrid Composites. Journal of University of Babylon for Engineering Sciences, 26(4):307-315.
[2] Hammed, M. G. and Khalaf, H. K. (2011). Studying tensile strength for epoxy composites reinforced with glass fibers. Iraqi Journal of Science, 52(3): 335-342.
[3] Hulugappa, B. et al. (2016). Effect of fillers on mechanical properties and fracture toughness of glass fabric reinforced epoxy composites. Journal of Minerals and Materials Characterization and Engineering, 4(1): 1-14.
[4] Oleksy, M. et al. (2014). Epoxy resin composite based on functional hybrid fillers. Materials, 7(8): 6064-6091.
[5] Ahmad, F. et al. (2015). A review: natural fiber composites selection in view of mechanical, light weight, and economic properties. Macromolecular materials and engineering, 300(1): 10-24.
[6] Srivastava, N. et al. (2013). Compressive behavior of walnut (Juglans L.) shell particles reinforced composite. Usak University Journal of Material Sciences,1:23-30 [7] Li, X. et al. (2007).Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. Journal of Polymers and the Environment, 15(1): 25-33.
[8] Alamri, H. and Low, I. M. (2012). Effect of water absorption on the mechanical properties of n-SiC filled recycled cellulose fibre reinforced epoxy eco-nanocomposites. Polymer Testing, 31(6):810-818.
[9] Ayrilmis, N. et al. (2013). Physical, mechanical, and thermal properties of polypropylene composites filled with walnut shell flour. Journal of Industrial and Engineering Chemistry, 19(3):908-914.
[10] Pirayesh, H. et al. (2012). The potential for using walnut (Juglans regia L.) shell as a raw material for wood-based particleboard manufacturing. Composites Part B: Engineering, 43(8):3276-3280.
[11] Srinivasan, A. and Viraraghavan, T. (2008). Removal of oil by walnut shell media. Bioresource technology, 99(17):8217-8220.
[12] Kashaninejad, M. et al. (2006). Some physical properties of Pistachio (Pistacia vera L.) nut and its kernel. Journal of Food Engineering, 72(1):30-38.
[13] Khantwal, R. et al. (2016). Walnut shell reinforced composite: a reviw. International Journal of Scientific Research, 7(5):179-189.
[14] Chandramohan, D. and Kumar, A. J. P. (2017). Experimental data on the properties of natural fiber particle reinforced polymer composite material. Data in brief, 13: 460-468.
[15] Gairola, S. et al. (2019). Impact behavior of pine needle fiber/pistachio shell filler based epoxy composite. In Journal of Physics: Conference Series , 1240(1): 012096. IOP Publishing.
[16] Alsaadi, M. et al. (2018). Effect of pistachio shell particle content on the mechanical properties of polymer composite. Arabian Journal for Science and Engineering, 43(9):4689-4696.
[17] Mohammed, A. J. (2014). Study the effect of adding powder Walnut shells on the Mechanical Properties and the flame resistance for Low Density Polyethylene (LDPE). International Journal of Science and Technology, 3(1):18-22.
[18] Hameed, H. K. (2017). Study of Mechanical and Thermal Behavior for Epoxy Reinforced by Fibers. Ibn AL-Haitham Journal For Pure and Applied Science, 28(1): 321-330.
[19] Husaen, S. I. and Jaffer, H. I. (2010). Effect of weight percentage chopped carbon fibers on the mechanism of cracks propagation for Epoxy composites. Iraqi Journal of Physics, 8(11):24-28.
[20] Salasinska, K. et al. (2018). Evaluation of highly filled epoxy composites modified with walnut shell waste filler. Polymer Bulletin, 75(6):2511-2528.
[21] Singh, V. K. (2015). Mechanical behavior of walnut (Juglans L.) shell particles reinforced bio-composite. Science and engineering of composite materials, 22(4):383-390.
[22] Nayak, S. Y. et al. (2017). Pistachio shell flakes and flax fibres as reinforcements in polyester based composites. In International Conference on Engineering and Information Technology, pp. 17-24.
[23] Singh, R. P. et al. (2010). Environmental degradation and durability of epoxy-clay nanocomposites. Journal of Nanomaterials, 2010.
[24] Onat, A. et al. (2013). Thermal and mechanical properties of walnut shell and glass fiber reinforced thermoset polyester composites. Asian Journal of Chemistry, 25(4):1947.
[25] Areef, S. R. (2008). The study of solution absorption and diffusion coefficient in epoxy composite reinforced with glass fibers. Engineering and Technology Journal, 26(10):1235-1240.
[26] Obidiegwu, M. U. et al. (2014). The effect of walnut shell powder on the properties of polypropylene filled composite. The International Asian Research Journal, 2(1):22-29.
[27] Sarsari, N. A. et al. (2016). Physical and mechanical properties of walnut shell flour-filled thermoplastic starch composites. BioResources, 11(3):6968-6983.