Viscometric Study of PC / PEG blends in THF solvent and Gamma-Rays Effect on the Viscosity of PC
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Abstract
In this research the intermolecular interaction between polycarbonate (PC) and polyethyleneglycol (PEG) in tetrahydrofuran (THF) solvent was studied, at 25˚C using a dilute solution viscometry method (DSV).
The reduced viscosity and intrinsic viscosity and viscosity interaction parameter (b) were experimentally measured, we also discuss the compatility of a polymer mixture in terms of , and the effect of gamma-rays on the reduced viscosity and intrinsic viscosity and Huggins constant of (PC). The results show that the relation between and C is liner within C=(0.9-2)g/dl, and viscometric constant KH decreases with irradiation time while increases with Tirr.
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References
[1] Mohammad, S.K.; Raina, A.Q. and Mian, S.W.
(2008). Afr. Journal pure Appl. Chem., 2:041-045.
[2] Omar, M.; Rajai, B.; Jamil, K.J.S.; Hani, H. and
Awin, El-k. (2003). chin. J. polym. Sci., 21:15-19.
[3] Zhang, Y.C. (2002). Eur. Polym. J., 38:333.
[4] Saha, S. (2001). Eur. Polym. J., 37:2513,
[5] Haiyang, Y.; Pingping, Z.; Minjun, H.; Shengli,
M. and Yuanyuan, W. (2000). Eur. Polym. J., 36:949.
[6] Garcia, R.; Melad, Q.; Gomez, C.M; Figueruelo,
J.E. and Campos, A. (1999). Eur. Polym. J., 35:4.
[7] Mathew, M.; Ninan, K.N. and Thomas, S. (1998).
Polymer, 39:6235.
[8] Abdel-Azim, A.A.; Bourtos, W.Y. and Abdel-
Bary., E.M. (1998). Polymer, 39:2543.
[9] Jiang, W.H. and Han, S.J. (1998). J. Polym. Sci,
part B, Polym. Phys., 36:1275.
[10] Ashok, K. et al. (2011). Mac. Mol. Theo. Simu.,
20:19-30.
[11] Catherine, A.K.; Andrew, N.; lisbeth, I. and
Kevin, M.S. (2012). Adv. Fun. Mat., 22:1984-1991.
[12] Halder, R.S.; Deopura, B.L. and Miro, A.
(2004). Polym. Eng. Sci., 29:1766-1773.
[13] Nita, L.E.; Chiriac, A.P.; Neamta, I. and Berea,
M. (2011). Phys. Engi. Asp., 374:121-128.
[14] Thinglu, M.; Guorong, S. and Songmin, S.
(2010). Journal Appl. Polym. Sci., 118:2572-2581.
[15] Nita, L.E.; Chiriac, A.P.; Neamta, I. Berea, M.
(2009). Phys. Engi. Asp., 348:254-262.
[16] Murat, M. and Ali, G. (2006). Journal Appli,
Polym. Sci., 100:4587-4594.
[17] Kumar, M.S.; Bhat, D.K. and Renganathan, N.G.
(2009). Journal Apply. Polym. Sci., 111:452-460.
[18] Kavlak, S.; Can, H.K. and Guner, A. (2004).
Journal Appl. Polym., 94:453-460.
[19] Rajulu, A.V. and Reddy, R.L. Journal Int.
Polym. Mater., 47:469-476.
[20] Erika, F.; Eniko, F. and Zoltan, L. (2012).
13:737-755.
[21] Yang, H.; Zhu, P.; Wang, S.; Zeng, Y. and Gou,
Q. (1998). Journal Eur. Polym., 34:1303-1308.
[22] Moore, W.R. and Uddin, M. (2003). Eur. Polym.
Journal, 5245.
[23] Cemil, A. and Ahmet, S.O. (2006). Journal
Alche., 52:3310-3314.
[24] Mamza, P.A.A.P. and Folaranmi, F.M. (1996).
Journal Eur. Polym., 32:909.
[25] Zhu, P.P. (1997). Journal Eur. Polym., 33:411.
[26] Lounis, M.Z.; Fromm, M.; Barillon, R.;
Chambaudet, M. and Allab, M. (2003). Journal
Randi. Meas., 36:615.
[27] Malinowski, K.; Skladnik, E. and Sadowski, M.
(2005). Journal Radi, Meas., 40:371.
[28] Nidal, D.; Toshiyuki, I.; Fuminobu, S. and
Yohei, I. (2007). Journal Nucl Inst. Meth., 572:826.
[29] Buni, M.S.; Solyman, W.A. and Ali, S.A.
(2013). Journal Edu. Sci., 26:40-48.
[30] Tager, A. (1978). Moscow physical chemistry of
pohymers.
[31] Kribaum, W.R. and Wall, F.T. (1950). Journal
Polym. Sci., 5:505.
[32] Abbas, M. and Reza, A. (2010). Journal Chem.
Eng. Data, 55:2537-2541.