Different analytical methods for estimating the heavy metals in fish products available in the Iraqi local markets by atomic absorption technique

Main Article Content

Hamad F. Musa Al – Jubouri
Sarhan A Salman

Abstract

The present study aims to estimate heavy metals (Cadmium, Lead, Copper, Zinc and Iron) by different analytical methods in local and imported fish products such as the following samples: (White tuna meat small pieces) Thailand produce, (Sardines with vegetable oil pepper, slices without heads) produced by Morocco, (Fish fillet without bones) Vietnam production (live Carp fish from ponds and live Carp fish from the Tigris River) Iraq production, and (Tuna cut small) Turkey production, The concentrations of above-mentioned elements in the target samples were determined by the flame atomic absorption device . Concentrations of heavy metals were estimated at (ppm) as follows : Cadmium values (0.48 - 2.05 ppm) , While Lead values (0.66- 2.90 ppm), The values of Zinc (2.99 - 19.14 ppm) , Copper values (0.15 - 2.66 ppm) , The values of Iron (15.47-3.28 ppm), The results showed that the best method of extraction was the method of digestion which showed better results than the other two methods (ultrasound method and Ashing method). The results showed that the levels of Cadmium and Copper in some products are higher than the limits allowed by the World Health Organization (WHO) and World Food Organization (FAO) while the values ​​of Lead, Iron and Zinc were within the limits allowed .

Article Details

How to Cite
Hamad F. Musa Al – Jubouri, & Sarhan A Salman. (2019). Different analytical methods for estimating the heavy metals in fish products available in the Iraqi local markets by atomic absorption technique. Tikrit Journal of Pure Science, 24(5), 18–24. https://doi.org/10.25130/tjps.v24i5.411
Section
Articles

References

[1] Hassan, A. A., abul Kareem, A., & Laftah, A. A. (2012). Integration Study of Vegetation Cover in Babil Governorate By Using Remote Sensing Data and GIS. J. Univ. Babylon, 22(1), 564-579.

[2] Dakhil N. Taha, Alaa K. H. Al-Khalaf, Ali L. Ali, (2012) . Determination of Pollution Level of Heavy Metals in some of Food Agricultural Plants, that irritated by Treatment Station for sewage water in Hilla City/ Iraq, Special Issue, J. Univ. Babylon.P23 [3] Cox, K. L., Meng, F., Wilkins, K. E., Li, F., Wang, P., Booher, N. J.& Zheng, Y. (2017). TAL effector driven induction of a SWEET gene confers susceptibility to bacterial blight of cotton. Nat. comm. 8, 15588.

[4] Conti, M. E., Mele, G., & Finoia, M. G. (2017). Baseline trace metals in Patella caerulea in a central Tyrrhenian ecosystem (Pontine Islands archipelago and Lazio region coastal sites, Italy). Env. Sci. Poll. Res. 24(9), 8852-8865.

[5] FAO, (2010). The international fish trade and world fisheries, http://www.fao.org /fileadmin / user_upload/ newsroom/ docs/ fact_sheet_fish_trade_en.pd . [6] Monferrán, M. V., Garnero, P., de los Angeles Bistoni, M., Anbar, A. A., Gordon, G. W., & Wunderlin, D. A. (2016). From water to edible fish. Transfer of metals and metalloids in the San Roque Reservoir (Córdoba, Argentina). Implications associated with fish consumption. Ecol. Indi. 63, 48-60.

[7] Abadi, D. R. V., Dobaradaran, S., Nabipour, I., Lamani, X., Ravanipour, M., Tahmasebi, R., & Nazmara, S. (2015). Comparative investigation of heavy metal, trace, and macro element contents in commercially valuable fish species harvested off from the Persian Gulf. Env. Sci. Poll. Res. 22(9), 6670-6678. [8] Gilbert, B., Hussain, E., Jirsa, F., & Avenant-Oldewage, A. (2017). Evaluation of trace element and metal accumulation and edibility risk associated with consumption of Labeo umbratus from the Vaal Dam, South Africa. Int. j. Env. Res. Pub. Heal.14(7), 678.

[9] Canli, M., and Atli, G. (2003). The relationships between heavy metal (Cd, Cr, Cu, Fe, Pb, Zn) levels and the size of six Mediterranean fish species. Env. Poll. 121(1), 129-136.

[10] Voegborlo, R.B. Methnani, A.M. andAbedin, M.Z. Mercury, (1999). Cadmium And Lead Content Of Canned Tuna. Food Chemistry 67 341-345.

[11] Salman, Ibrahim Mahdi Azzouz and Zeinab Ali Habibullah, (2011). Evaluation of the level of heavy elements in canned tuna meat and its preservative medium, Spa. J.(Res. Appl. Sci.) 10(2). . [12] Georgieva, E., Stoyanova, S., Velcheva, I., Vasileva, T., Bivolarski, V., Iliev, I., & Yancheva, V. (2014). Metal effects on histological and biochemical parameters of common rudd (Scardinius erythrophthalmus L.). Arch. Polish Fish. 22(3), 197-206.

[13] Jaccob, A. A. (2016). Assessment of Heavy Metals (Cd, Fe, Cu and Zn) levels in Oreochromis aureus and Cyprins Carpio fish species collected from Shat El-Arab River, Basra-Iraq, as possible indicator of heavy metals toxicity. Thi-Qar Med. J. 11(1), 142-155.

[14] Demirel, S., Tuzen, M., Saracoglu, S., & Soylak, M. (2008). Evaluation of various digestion procedures for trace element contents of some food materials. J. Haz. Mat.152(3), 1020-1026.

[15] Akinyele, I. O. and Shokunbi, O. S. (2015). Comparative analysis of dry ashing and wet digestion methods for the determination of trace and heavy metals in food samples. Food chemistry, 173, 682-684.

[16] Houser, K. L., Donofrio, W. T. and Stulen, F. B. (2017). U.S. Patent No. 9,675,375. Washington, DC: U.S. Patent and Trademark Office.

[17] FAO/WHO, (2011). Evaluation of certain food additives and the contaminants mercury, lead and cadmium, WHO Technical Report, Series No. 966.