Electrical Conductance Study of Aspartic Acid (Asp) Complex Cobalt (Co ΙΙ ) in Different Solvents and Temperatures
Article Sidebar
Main Article Content
Abstract
The electrical conductivities of Co(II) complex with aspartic acid (Asp) in different solvents (water, methanol and ethanol) at different temperatures were measured by assisting of lee-Wheaton equation at the best fit values of standard deviled for analyzing the data of unsymmetrical electrolytes including,the conductivity parameters, the ionic conductivity M+2, the association constant KA, and the distance parameter R .
Thermodynamic information from association and examining the nature of the interaction was obtained.
Article Details
This work is licensed under a Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
References
1- M. Q. ehsan., M. Jcbin, E. Ahmed and M. A,
Quyser , Indian Journal of Chemistry 38A (1999) pp.
826-828.
Y. Fukuda, K. Sone.Bull.Chem.Soc.Jap45 (1972) 465 .
3- M. Von Meter, H.M. Newman , J.Amer. Chem.
Soc. 98(1976) 1382 .
4- E. Iwamoto, Y. Yamahato. Inorganic Nucl. Chem.
Lett. 13(1977) 399.
5- T.J. Tominago. Phys. Chem. 79 (1975)16-20,
1664-1670.
6- S. Newmann,, E.B. Blinn, L.J. Carison. Phys.
Chem., 83(1979) 676.
7- Ito, K.; Iwamoto, I. and Yamahato, Y., Bull.
Chem. Soc.Jpn., 55(1982) 3190.
8- Y.O. Hameed, S. M. Saied, H. A. Abedel-Rahman,
J. Raf. Sci.,23(2012) 2,53-71.
9- S. Subhasish, D. Dharumaduri, C. Sarvanan and P.
Annamalai, Physics, Chemistry and Technology 7,
No 1( 2009) pp. 73 – 80.
10- D.D. Perrin, W.L.F. Armarego, and D.R. Perrin
1st Ed., Pergamon Press, Oxford, (1966) p. 199.
11- G.Jones, and B.C. Bradshow, J. Phys. Chem. 55
(1933) 1780.
12- P. Hemmes, J. Phys. Chem. 78, 9 (1974) p 907-
90.
13- W.H.; Lee and Wheaton R.J., J. Chem. Soc.,
Faraday Trans,11, 74(1978) 743.
14- Ammar Abd-Aljabar Aziz ; Preparation of New
transition and non
Transition metals complexes with N-acetylglucose
amine(NAGA; Iraqi National Journal of Chemistry;
2013 volume50,191198.
15-R.A. Robinson and R.H. Stokes, ،،Electrolyte Solution،، .Butter worth, London,112(1966).
16- H. A. Abedel-Rahman, Thesis, ،،An Electrical conductometric study of some Amino Acids and Their complexes with some Metales in Aqueous Medium at different temperatures (2007), Mosul,Iraq.
17- P. J. Hemes. Phys. Chem., 78(1974) 904.
18- B. A. Akrawi and Y.O. Hameed, J. National. Chemistry, 31 (2008) 447- 454.
19- B. A. Akrawi and A. M. J.Ali, J. National. Chemistry, 31 (2008)491-500.