Preparation and characterization of some Transition Metal Complexes the first and second with (1-methyl-3-Piperidine Xanthate potassium) and ethylenediamine
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Abstract
This research includes the preparation of a number of new tetra xanthate complexes diheterometal of some transition metal of Co(II), Ni(II), Cu(II), and non transition metal of Zn(II) and Cd(II) by reacting the metal salts with the ligand (1-methyl-3-piperidine xanthate) to form complexes of formula of [M{Ag(1-Me-3-pipXant)2}2] (A), [MM`(1-Me-3-pipXant)4] (B), where M=Co(II), Ni(II), Cu(II), M`= Cd(II), Zn(II) and These complexes were reacted with ethylendiamine to form an adduct of the general formula [M(en)3][M(1-Me-3-pipXant)2}2] (I.A), [M(en)3][M`(1-Me-3-pipXant)4] (I.B). All the prepared complexes have been characterized and studied by element analysis, molar conductance, magnetic susceptibility, infrared and electronic spectral.
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References
1. W.v. Malik, R. Bembi and V.K. Bhrdwaj, J.
Indian Chem. Soc., 57, 35, (1980).
2. M.R. Chaurasia, A.K. Sharma and S.K. Sharma,
J. Indian Chem. Soc., 58, 687, (1981).
3. M. Sarmini, M. Sc. Thesis, University of Aleppo,
(1999).
4. A.I.V. Vogel, "A Text Book of Practical
Organic Chemistry" 3rd ed., 499, (1985).
5. K.A. Hassal, "The Chemistry of Pesticides their
Metabolism Mode of Action and Uses in Crop
Production", Macmillan London, 197, (1982).
6. V. Tmecka, M. Harchovcova, A. Humplik and I.
Orlik, Czech. CS 254, 154, (1988), Chem. Abs., 110,
214568e, (1989).
7. I. Ara, F. El-Bahij, Transition Metal Chemistry,
28, 908-912, (2003).
8. Marius V. Campiar, Ionel Haiduc; Edward R.T.
Tiekink, J. Chem. Crystallorgraphy, 40,11,1029-
1034, (2010).
9. G. Rajput, V. Singh, S.K. Singh, Lal B. Prasad,
M.G.B. Drew and N. Singh., European Journal of
Inorganhc Chemistry, 24, 3885-3891, (2012).
10. A.F. Kazzer, I.A. Mustafa and S.E. Al-Mukhtar,
J. Iraqi. Chem. Soc., 12, 3, 5, 171, (1987).
11. L.H. Little, G.W. Poling and J. Lejal, Can. J.
Chem., 39, 1783, 754, (1961).
12. G. Winter, Rev. Inorganic. Chem., "Inorganic
Xanthate", 2, 253, 263, 267, (1980).
13. R.C. Aggawal, N. Singh and S.S. ingh, Indian J.
Chem., 21A, 268, (1982).
14. A.F. Kazzer, S.E. Al-Mukhtar and I.A. Mustafa,
Iraqi J. Chem., 14, 34, (1989).
15. R.C. Aggarwal, N. Singh and S. Singh,
Polyhedron, 4, 343, (1985).
16. D. C. oucovanis and J.P. Fackler, J. Inorg.
Chem., 6, 2047, (1967).
17. R.N. Murty, R.N. Dash and D.V. Ramara, Rao, J.
Indian Chem. Soc., 61, 934, 945, (1984).
18. R.N. Ansari, M.C. Jain M.C. Jain, and W.V.
Malik, J. Indian Chem. Soc., 57, 861, (1980).
19. B. Singh and U. Srivastava, Indian J. Chem.,
28A, 431, (1989).
20. N. Singh, N.K. Singh and C. Kaw, Bull. Chem.
Soc. Jpn, 62, 3328, (1989).
21. R.C. Aggarwal, N. Singh and S. Singh,
Polyhedron, L, 343, (1985).
22. R.C. Aggarwal, N. Singh and S. Singh, Indian J.
Chem., 22A, 161, (1983).
23. M.R. Hunt, A.G. Kruger, L. Smith and G. Winter,
Aust, J. Chem., 24, 53, (1971).
24. R.H.K. Varma and C.P. Prabhakaron. Indian J.
Chem., 28A, 119, (1989).
25. B. Singh and V. Srivastava, Indian J. Chem.,
28A, 431, (1989).
26. G.W. Watt and B.J. Mccormick, Spectro. Chem.
Acta., 21, 553, 753, (1965).
27. D. Coucouvanis, Prog. Inorg. Chem., 11, 233,
(1970).
28. R.C. Aggarwal, B. Singh and M.K. Singh, J.
Indian Chem. Soc., 59, 269, (1982).
29. B.N. Figgis and R.S. Nyholn, J. Chem. Soc., 12,
(1954).
30. B.B. Kaul and K.B. Pandeya, J. Inorg. Nucl.
Chem., 40, 1035, (1978).
31. B.N. Figgis and J.Lewis, "Progress in Inorganic
Chemistry", 6, 18, 37, (1964).
32. R.L. Carlin Transit. Met. Chem., 1, 28, (1965).
33. D.G. Holah and C.N. Murphy, Inorg. Nucl.
Chem. Let., 1069, (1978).
34. D. Nicholls, "The Chemistry of Iron, Cobalt
and Nickel", 1st ed., Pergamon Press, Oxford,
pp.1037, 1070, 1087-1091, 1093, 1151, 1153, 1154,
(1973).
35. B.N. Figgis and J.Lewis, "Modern Coordination
Chemistry", Interscience, New York, 400, (1460).
36. S.K. Dawood, M. Sc. Thesis, University of
Mosul, (1986).
37. K. Bizilj, S.G. Hardin, B.f. Hoskins, P.J. Oliver,
R.T. Edward and G. Winter, Aust. J. Chem., 39,
1035, 919860.
38. R.W. Gablea and G. Winter, Inorg. Nucl. Chem.
Lett., 16, 9, (1980).
39. R.W. Adams, C.G. Barraclough, R.L. Martin and
G. winter, Aust. J. Chem., 20, 2351, (1967).
40. C.E. Manoussakis and C.A. Bolosm, Inorg.
Chim. Acta, 108, 215, (1985).
41. A.C. Mossey and B.F. Jhonson, "The chemistry
of copper, silver and gold", Pergman Press, Oxford,
20, 41, (1975).
42. N. Saha and N.C. Gayen, J. Indian Chem. Soc.,
LX, 317, (1983).
43. D. sellman, P. Ball, F. Knoch and M. Moll, Z.
Natnr Forsch, 50b, 791, (1995).
44. B.S. Manhas, S. bala, R. Jaganathan and a.s.
Dindsa, Indian J. Chem., 28a, 258, (1989).
45. G.St. Nikolor and M.A. Atanasov, J. Inorg. Nucl.
Chem., 43, 1201, (1981).
46. B.N. Chawik and A.G. Sharpe, Adv.Inorg. And
Radio Chem., 8, 33, (1957).
47. M.R. Gopakrishnam and C.P. Prabhakaran, J.
Inorg. Nucl. Chem., 43, 3390, (1981).