The effect of UV – Radiation on Thermal and Mechanical Properties of (PP/LDPE) Blends

Main Article Content

Balkees M. Aldabbagh
Hanaa J. Al shimary
Adnan R. Ahmmed

Abstract

UV-rad effected on thermal and mechanical properties (density, Shore D hardness, melt flow index, DSC) properties were studied for polypropylene (PP) blended with low density polyethylene (LDPE) at different ratios (10% PP+90% LDPE), (25%PP+75%LDPE). Results shows decreasing of blend density with increasing of  PP content and increasing  of it  after UV-RAD for (15 hr.), also Shore D hardness decreased at the first ratio of  PP (10%) then it increased with increasing of PP contain. Also Shore D increases after UV rad for (15 hr.). Melt flow index (MFI) decreased after UV rad, also the UV rad leads to increasing of crystallinity regions of blends.

Article Details

How to Cite
Balkees M. Aldabbagh, Hanaa J. Al shimary, & Adnan R. Ahmmed. (2023). The effect of UV – Radiation on Thermal and Mechanical Properties of (PP/LDPE) Blends. Tikrit Journal of Pure Science, 21(1), 71–75. https://doi.org/10.25130/tjps.v21i1.952
Section
Articles

References

[1] D. Nwabunma and Th. Kyu, " Polyolefin Blends", ISBN: 978-0-471-79058-7, Jan. (2008). [2] D. G. Dikobe and A. S. Luyt, " Comparative study of the morphology and properties of PP/LLDPE/wood powder and MAPP/LLDPE/wood powder polymer blend composites", EXPRESS Polymer Letters Vol.4, No.11 PP, (729–741), (2010). [3] L. Utraki, " Commercial Polymer Blends", Springer – Verlag, PP (80-90), USA. (1998). [4] J. Li and R. Shanks," Time-dependent Morphology of Polyethylene – Polypropylene Blends", Chinese Jour. of Poly. Sci., Vol. 20, No. 6, PP(497-508). (2002).

[5] A. V. Shenoy and D. R. Saini, "Thermoplastic Melt Rheology and Processing", Marcel Dekker Inc., New York. (1996).

[6] Das, P K, DesLauriers, P J, Fahey, R, Wood, F K & Coruforth, F J, "Photostabilization of poly(p-phenylene sulfide), Polymer Degradarion and Stability", pp (1 – 10), (1994). [7] I. Z. Liang and J. N. Ness, "Investigation on the melt flow properties of polyethylene and polypropylene blends", Polymer Testing, Vol. 16, PP (379-389), (1997). [8] A. Dhoble, B. Kulshreshtha, S. Ramaswami and D.A. Zumbrunnen, "Mechanical properties of PP-LDPE blends with novel morphologies produced with

a continuous chaotic advection blender", Polymer, Vol. 46 PP( 2244–2256), (2005). [9] N. Saleh, N. A. Mohammed and Weam A.Abed, "Studing of Some Phisical Properties and Morphology of Blends of Hdpe /Lldpe after and before Exposure to UV Light", Eng. & Tech. Journal ,Vol.27, No.4, (2009). [10] P. Zamotaev , I. Chodak , O. Mityukhin and I. Chorvath, "Photoinduced crosslinking of polyolefine blends. I. Crosslinking of LDPE, PP, and LDPE/PP blends", Journal of Applied Polymer Science, Vol. 56, Issue 8, pages 935–946, (23 May 1995).

[11] Sihama E. Salih1, Abdullkhaliq F. Hamood1 & Alyaa H. Abd alsalam, "Comparison of the Characteristics of LDPE : PP and HDPE : PP Polymer Blends", Modern APPlied Science; Vol. 7, No. 3, (2013). [12] P. C. Lodi, B. S. Bueno, O. M. Vilar "Evaluation of Geomembrane UV Degradation Using Melt Flow Index and Oxidative Induction Time Tests", Proceeding of the 4th Asian Regional Conference Geosynthetics , June 17-20 Shanghai-China. (2008). [13] I. Borovanska, R Krastev, R Benavente, M. Pradas, A. Valle´s Lluch, V.Samichkov and M. Iliev, "Ageing effect on morphology, thermal and mechanical properties of impact modified LDPE/PP blends from virgin and recycled materials", Journal of Elastomers & Plastics, PP (427–447) ,Vol. 46(5), (2014).

[14] AT No. 86, "DSC Measurement of Polypropylene", Hitachi High Tech. Science Corporation (2008).

[15] Sh. Luzuriaga, "Utilization of Compatiplization and Restablization Methods in The Recycling of Commingled Municipal Plastic Waste", Masaryk University in Brno, (2009).