Effect of Al doping on the Structural properties of SnO2 thin films prepared by (sol-gel) method

Main Article Content

Najat A. Dahham
Ali Esmaeel
Nawal Ali Abed

Abstract

Undoped and Al-doped SnO2 thin films have been prepared by sol–gel spin coating process on glass substrate  for different doping (0, 2.5 ,5 ,7.5,10)% The starting precursor was used as tin chloride dihydrate (SnCl2.2H2O), ethanol , with and without stabilizer. As annealing in a temperature 500°C for one hours, the results of (X-Ray ) diffraction showed that the films have a Polycrystalline structure and increased intensity when use  stabilizer and orientation was (020) with lattice constants (a=4.796, b=5.796, c= 5.193) Å.


  The surface morphology of the (SnO2: Al) thin films have been studied using atomic force microscopy (AFM) which indicated that the grown films showed good crystalline and homogeneous surface. The Root Mean Square (RMS) values and surface roughness of the films increased with increasing doped concentration specify when use  stabilizer.

Article Details

How to Cite
Najat A. Dahham, Ali Esmaeel, & Nawal Ali Abed. (2023). Effect of Al doping on the Structural properties of SnO2 thin films prepared by (sol-gel) method. Tikrit Journal of Pure Science, 21(3), 155–161. https://doi.org/10.25130/tjps.v21i3.1009
Section
Articles

References

1- S. Ebrahimiasl, A. Zakaria, "Simultaneous Optimization of Nanocrystalline SnO2 Thin Film Deposition Using Multiple Linear Regressions", Sensors, 14, 2549-2560, ( 2014).

2-S.Yousif,J.Abass,"Structural, Morphological and Optical Characterization of SnO2:F thin films prepared by Chemical spray Pyrolysis" International Letters of Chemistry, vol 13,90-102,(2013).

3- J. Besenhard, J. Yang, M. Winter "advanced lithium-alloy anodes have a chance in lithium-ion batteries". JPower Sources, 68(1), 87−90, (1997).

4- O. Crosnier, T. Brousse, X. Devaux, P. Fragnaud, D. Schleich "New anode systems for lithium ion cells". Power Sources, 94(2), 169−171, (2001).

5- J. Tirado, "Inorganic materials for the negative electrode of lithium-ion batteries State-of-the-art and future prospects",. Mater Sci Eng R, 40(3), 103−115, (2003).

6- Y. Zheng-yong, Y. Liang-jie, S. Ju-tang., "Synthesis and properties of nanosized tin-zinc composite oxides as lithium storage materials", Chemical Journal of Chinese Universities, 27(12), 2252 − 2255, (2006).

7-Y. Zhao, S. Qin," Nanocrystalline tin oxides and nickel oxide film anodes for Li-ion batteries". J. Power Sour., 114, 113,( 2003).

8- S. Ali, S. Hussain, S. Bakar, J. Muhammad, ,N. Rehman, "Effect of doping on the Structural and Optical Properties of SnO2 Thin Films fabricated by Aerosol Assisted Chemical Vapor Deposition" Journal of Physics: Conference Series 439,(2013).

9- M. Aziz, S. Abbas, S. Baharom, " Size-controlled synthesis of SnO2 nanoparticles by sol-gel method", Mater. Lett., 91, 31–34,( 2013).

10- J. Szanyi,"The origin of haze in CVD tin oxide thin films", J. Appl. Surf. Sci., 185, 161,( 2002).

11- M. Wagner, T. Kohl, C. Fröba,"Gas sensing properties of ordered mesoporous SnO2",J. Sens., 6, 318–323,( 2006).

12- H. Köse, A. Aydin, H. Akbulut, "Sol–Gel Synthesis of Nanostructured SnO2 Thin Film Anodes for Li-Ion Batteries", Acta physica polonicaa, Vol. 121, No. 1, (2012).

13-K.Joy, S. Lakshmy, P. Thomas, "Band gap tuning in nanocomposite ZrO2-SnO2 thin films achieved through sol-gel co-deposition method", Journal of Sol-Gel Science and Technology, Volume 61, Issue 1, pp 179-184 ,(2012).

14- R. Bari, S. Patil, A. Bari," Synthesis, characteracterization and gas sensing performance of sol-gel prepared nanocrystalline SnO2 thin films" International journal on smart sensing and interlligent systems ,vol 7 ,No 2 (2014).

15- A. Kocyigit, D. Tatar ,and Others, "Highly efficient Optoelectronic properties of doubly doped SnO2 thin film deposited by spin coating technique" ,Journal of ovonic research , Vol.8,No.6,(2012).

16-M.T. Al-Msaybawee, "Study The Piezoelectric Properties of SnO2 Thin Films Prepared by Spray Pyrolysis", M.Sc. Thesis, College of Science Al- Mustansiriyah University,(2011).